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Título : | Phase transformation, thermal behavior, and magnetic study of new (FeSiBP)100-XCuX glassy alloys obtained by melt-spinning in air |
Autor : | Perea Cabarcas, Darling Echeverría Echeverría, Félix Bolívar Osorio, Francisco Javier Parra Vargas, Carlos Arturo |
metadata.dc.subject.*: | Metallic glasses Aleaciones magnéticas Magnetic alloys Materiales magnéticos Magnetic materials Vidrio Glass Propiedades magnéticas Magnetics properties http://id.loc.gov/authorities/subjects/sh85084121 |
Fecha de publicación : | 2023 |
Editorial : | Springer |
Citación : | Perea C., Darling & Vargas, C. & Echeverría, F. & Osorio, F.. (2023). Phase transformation, thermal behavior, and magnetic study of new (FeSiBP)100-XCuX glassy alloys obtained by melt-spinning in air. Journal of Materials Research. 38. 10.1557/s43578-023-01055-0. In the current work, a new variation of the FeSiBPCu system with good glass forming ability and soft magnetic properties was developed and investigated. The effect of copper addition on the FeSiBP base alloy was studied in the system (Fe 0.77 Si 0.08 B 0.1 P 0.05 ) 100-x Cu x with x = 0, 0.25, 0.5, 0.75 and 1.0 at%. Microstructural evolution upon the annealing process was evaluated by XRD and TEM, revealing the formation of α-Fe(Si), Fe 2 B and Fe 3 (B,P) crystalline phases. VSM allowed to determine that the combination of chemical composition and microstructure with the best soft magnetic properties after the annealing corresponds with the alloy with 0.75% Cu. In addition, activation energy for glass transition and the first crystallization event were calculated using the Kissinger method. The research findings demonstrated that maintaining the relationship between the main elements, it is possible to keep the good glass forming ability with the possibility of developing a nanocrystalline structure with soft magnetic performance. Graphical abstract |
Resumen : | ABSTRACT: In the current work, a new variation of the FeSiBPCu system with good glass forming ability and soft magnetic properties was developed and investigated. The efect of copper addition on the FeSiBP base alloy was studied in the system (Fe0.77Si0.08B0.1P0.05)100-xCux with x=0, 0.25, 0.5, 0.75 and 1.0 at%. Microstructural evolution upon the annealing process was evaluated by XRD and TEM, revealing the formation of α-Fe(Si), Fe2B and Fe3(B,P) crystalline phases. VSM allowed to determine that the combination of chemical composition and microstructure with the best soft magnetic properties after the annealing corresponds with the alloy with 0.75% Cu. In addition, activation energy for glass transition and the frst crystallization event were calculated using the Kissinger method. The research fndings demonstrated that maintaining the relationship between the main elements, it is possible to keep the good glass forming ability with the possibility of developing a nanocrystalline structure with soft magnetic performance. |
metadata.dc.identifier.eissn: | 2044-5326 |
ISSN : | 0884-2914 |
metadata.dc.identifier.doi: | 10.1557/s43578-023-01055-0 |
Aparece en las colecciones: | Artículos de Revista en Ingeniería |
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Fichero | Descripción | Tamaño | Formato | |
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PereaDarling_2023_PhaseTransformationThermal.pdf | Artículo de investigación | 2.7 MB | Adobe PDF | Visualizar/Abrir |
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